Papers measuring tropospheric HCl published

Two papers from our team related to tropospheric hydrogen chloride (HCl) were recently published. HCl represents the primary gaseous reservoir of reactive chlorine, which has been shown to impact air quality. As a highly surface-active gas, obtaining accurate measurements of gaseous HCl is challenging.

A paper led by Teles validated a new commercial spectroscopic instrument for the measurement of tropospheric HCl. He performed laboratory and ambient intercomparisons to demonstrate the accuracy and precision of this robust and compact new instrument. The paper was published in Atmospheric Measurement Techniques.

Another paper led by Andrea used the same commercial instrument to make measurements of HCl in a coastal city (St. John’s, NL) in the spring and a continental city (Toronto, ON) in the winter. By comparing the HCl measurements with co-located supporting measurements and a global model, we can better understand the sources of HCl in these areas. The paper was published in ACS Earth & Space Chemistry.

The HCl analyzer in action.

The HCl analyzer in action.

Collaborative papers published

Members of the group are often busy working on papers with our collaborators. Three papers have been recently published:

A paper describing a new calibration source for HONO that generates stable, atmospherically-relevant levels was recently published in Atmospheric Measurement Techniques: Lao, M., Crilley, L.R., Salehpoor, L., Furlani, T.C., Bourgeois, I., Neuman, A., Rollins, A.W., Veres, P.R., Washenfelder, R.A., Womack, C.C., Young, C.J., VandenBoer, T.C.* A portable, robust, stable and tunable calibration source for gas-phase nitrous acid (HONO). Atmospheric Measurement Techniques.

A new analysis of data collected during the CalNex campaign in 2010 examining budgets of total reactive carbon was put together by Colette Heald of MIT and published in Environmental Science and Technology: Heald, C.L.,* de Gouw, J., Goldstein, A.H., Guenther, A.B., Hayes, P.L., Hu, W., Isaacman-Vanwertz, G., Jimenez, J.L., Keutsch, F.N., Koss, A.R., Misztal, P.K., Rappengluck, B., Roberts, J.M., Stevens, P.S., Washenfelder, R.A., Warneke, C., Young, C.J. Contrasting reactive organic carbon observations in the southeast United States (SOAS) and southern California (CalNex). Environmental Science and Technology.

The first paper from the Reactive Oxidants from Cleaning in a Chamber (ROCC) campaign was recently published, demonstrating the impact of non-bleach cleaners on gas-phase hydrogen peroxide: Zhou, S., Liu, Z., Wang, Z., Young, C.J., VandenBoer, T.C., Guo, B., Zhang, J., Carslaw, N., Kahan, T.F.* Hydrogen peroxide emission and fate indoors during non-bleach cleaning: A chamber and modeling study. Environmental Science and Technology.

The timely release of this cleaning study garnered attention from the media, with articles in CBC and other media outlets.

Members of the ROCC team hard at work during the measurement intensive.

Members of the ROCC team hard at work during the measurement intensive.

Group attends SETAC North America meeting in Toronto

This year’s Society of Environmental Toxicology and Chemistry (SETAC) North America meeting was held in Toronto in early November. Joseph, Teles, Devon, Jessica, Daniel, Alex, and Elizabeth (in absentia) all presented their work. Special congratulations to Devon and Daniel who won presentation awards!

Dinner for group and alumni during SETAC. Thanks to Robbie D for this classic group selfie!

Dinner for group and alumni during SETAC. Thanks to Robbie D for this classic group selfie!

Daniel presents his poster at SETAC (photo credit A. De Silva).

Daniel presents his poster at SETAC (photo credit A. De Silva).

Making new friends at SETAC.

Making new friends at SETAC.

Cora in Washington DC at AAAS symposium

Cora was in Washington DC this week to present at the American Academy for the Advancement of Science (AAAS) Chemistry in Indoor Environments Symposium. She discussed several projects from the group, including work by current and former students Daniel, Heidi, Kat, and Devon. More information about the symposium can be found here.

Panelists for Panel 4: Indoor Chemistry Problems and Solutions (credit: Glenn Morrison)

Panelists for Panel 4: Indoor Chemistry Problems and Solutions (credit: Glenn Morrison)

Cora discusses measurements made indoors in Syracuse NY (credit: Marina Vance)

Cora discusses measurements made indoors in Syracuse NY (credit: Marina Vance)